Annotating a large-scale image dataset is very tedious, yet necessary for training person re-identification models. To alleviate such a problem, we present an active hard sample mining framework via training an effective re-ID model with the least labeling efforts. Considering that hard samples can provide informative patterns, we first formulate an uncertainty estimation to actively select hard samples to iteratively train a re-ID model from scratch. Then, intra-diversity estimation is designed to reduce the redundant hard samples by maximizing their diversity. Moreover, we propose a computer-assisted identity recommendation module embedded in the active hard sample mining framework to help human annotators to rapidly and accurately label the selected samples. Extensive experiments were carried out to demonstrate the effectiveness of our method on several public datasets. Experimental results indicate that our method can reduce 57%, 63%, and 49% annotation efforts on the Market1501, MSMT17, and CUHK03, respectively, while maximizing the performance of the re-ID model.