The analysis of the night cloud cover is very important for astronomical observation in real time, considering a typical observation time of about 15 minutes, and to have a statistics of the night cloud cover. In this paper we use the SQM (Sky Quality Meter) for high resolution temporal analysis of the La Silla and Asiago (Ekar observatory) sky: 3 and 5 minutes respectively. We investigate the annual temporal evolution of the natural contributions of the sky in a site not influenced by artificial light at night (ALAN) and one highly influenced respectively. We also make a correlation between GOES and AQUA satellites data and ground-based SQM data to confirm a relationship between the SQM data and cloud cover. We develop an algorithm that allows the use of the SQM for night cloud detection and we reach a correlation of 97.2% at La Silla and 94.6% at Asiago with the nighttime cloud cover detected by the GOES and AQUA satellites. Our algorithm also classifies the photometric (PN) and spectroscopic nights (SN). We measure 59.1% PN and 21.7% SN for a total percentage of clear nights of 80.8% at La Silla in 2018. The respective Ekar observatory values are 31.1% PN, 24.0% SN and 55.1% of total clear nights time. Application to the SQM network would involve the development of long-term statistics and big data forecasting models, for site testing and real-time astronomical observation.
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