We prove that K-polystable log Fano pairs have reductive automorphism groups. In fact, we deduce this statement by establishing more general results concerning the S-completeness and $Theta$-reductivity of the moduli of K-semistable log Fano pairs. Assuming the conjecture that K-semistability is an open condition, we prove that the Artin stack parametrizing K-semistable Fano varieties admits a separated good moduli space.