We investigate asymptotically safe extensions of the Standard Model with new matter fields arising in the TeV energy range. The new sector contains singlet scalars and vector-like fermions in representations which permit Yukawa interactions with the Standard Model leptons. Phenomenological implications are explored including charged lepton flavour violation, Drell-Yan processes and lepton anomalous magnetic moments. For the latter, we find that BSM contributions can be sizeable enough to explain the present experimental discrepancies of the electron and muon anomalous magnetic moments with the Standard Model.