Semiconductor interfaces, such as these existing in multilayer structures (e.g., quantum wells (QWs)), are interesting because of their ability to form 2D electron gases (2DEGs), in which charge carriers behave completely differently than they do in the bulk. As an example, in the presence of a strong magnetic field, the Landau quantization of electronic levels in the 2DEG results in the quantum Hall effect (QHE), in which Hall conductance is quantized. This chapter is devoted to the properties of such 2DEGs in multilayer structures made of compound semiconductors belonging to the class of Se- and Te-based chalcogenides. In particular, we will also discuss the interesting question of how the QHE phenomenon is affected by the giant Zeeman splitting characteristic of II-VI-based diluted magnetic semiconductors (DMSs), especially when the Zeeman splitting and Landau splitting become comparable. We will also shortly discuss novel topological phases in chalcogenide multilayers.
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