With recent advances in dynamic scanning probe microscopy techniques, it is now a routine to image the sub-molecular structure of molecules with atomically-engineered tips which are prepared via controlled modification of the tip termination and are chemically well-defined. The enhanced spatial resolution is possible as atomically-engineered tips can preserve their integrity in the repulsive interaction regime. Although the mechanism of improved spatial resolution has been investigated both experimentally and theoretically, the ultimate temporal resolution while preserving picometer scale spatial resolution still remains an open question. Here, we computationally analyze the temporal resolution of atomic force microscopy imaging with atomically-engineered tips. Our computational results reveal that non-metal terminated tips, e.g. oxygen-terminated copper, are well-suited for enhanced temporal resolution up to video rate imaging velocities while preserving picometer range spatial resolution. Contrarily, the highest-attainable spatial resolution of atomically-engineered tips with low-stiffness, e.g. CO-terminated, deteriorate with increasing imaging velocity. Our results reveal that when atomically-engineered tips terminated with molecules are in use, imaging velocities in the order of nanometers per second at most are inevitable even for atomically flat surfaces to retain atomic resolution and avoid slip-stick motion. In addition to shedding light on the temporal resolution of atomic force microscopy imaging with atomically-engineered tips, our numerical results provide an outlook to the scalability of atom-by-atom fabrication using scanning probe microscopy techniques.
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