Emission at 4.6 um was observed from an N2O filled hollow core fiber laser. 8-ns pump pulses at 1.517 um excited a vibrational overtone resulting in lasing on an R and P branch fundamental transition from the upper pump state. At optimum gas pressure of 80 Torr a photon conversion efficiency of 9% and a slope efficiency of 3% was observed from a mirrorless laser. The laser threshold occurred at an absorbed pump energy of 150 nJ in a 45-cm long fiber with 85 {mu}m core diameter. The observed dependence of the laser output on gas pressure is shown to be a result of line broadening and relaxation rates.
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