We investigated LaFeAsO single crystals by means of synchrotron Mossbauer spectroscopy under pressures up to 7.5 GPa and down to 13 K and provide a microscopic phase diagram. We found a continuous suppression of the magnetic hyperfine field with increasing pressure and it completely vanishes at $sim$ 7.5 GPa which is in contrast to the behavior in polycrystalline samples where the magnetic order vanishes at $sim$ 20 GPa. The different behavior of the polycrystalline samples might be due to As-vacancies. Our results are in qualitative agreement with density functional theory calculations where a reduction of the magnetic moment with increasing pressure was found. We found that among different samples at ambient pressure the magnetic phase transition temperature as well as the low-temperature magnetic hyperfine field decrease with increasing unit cell volume.
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