Electron pairing due to a repulsive Coulomb interaction in a triple quantum dot (TQD) is experimentally studied. It is found that electron pairing in two dots of a TQD is mediated by the third dot, when the third dot strongly couples with the other two via Coulomb repulsion so that the TQD is in the twofold degenerate ground states of (1, 0, 0) and (0, 1, 1) charge configurations. Using the transport spectroscopy that monitors electron transport through each individual dot of a TQD, we analyze how to achieve the degeneracy in experiments, how the degeneracy is related to electron pairing, and the resulting nontrivial behavior of electron transport. Our findings may be used to design a system with nontrivial electron correlations and functionalities.