Point contact tunneling (PCT) spectroscopy measurements are reported over wide areas of cm-sized cut outs from niobium superconducting RF cavities. A comparison is made between a high-quality, conventionally processed (CP) cavity with a high field Q drop for acceleration field E $>$ 20 MV/m and a nitrogen doped (N-doped) cavity that exhibits an increasing Q up to fields approaching 15 MV/m. The CP cavity displays hot spot regions at high RF fields where Q-drop occurs as well as unaffected regions (cold spots). PCT data on cold spots reveals a near ideal BCS density of states (DOS) with gap parameters, $Delta$ as high as 1.62 meV, that are among the highest values ever reported for Nb. Hot spot regions exhibit a wide distribution of gap values down to $Delta sim$ 1.0 meV and DOS broadening characterized by a relatively large value of pair-breaking rate, $Gamma$, indicating surface regions of significantly reduced superconductivity. In addition, hot spots commonly exhibit Kondo tunneling peaks indicative of surface magnetic moments attributed to a defective oxide. N-doped cavities reveal a more homoegeneous gap distribution centered at $Delta sim$ 1.5 meV and relatively small values of $Gamma/Delta$. The absence of regions of significantly reduced superconductivity indicates that the N interstitials are playing an important role in preventing the formation of hydride phases and other macroscopic defects which might otherwise severely affect the local, surface superconductivity that lead to hot spot formation. The N-doped cavities also display a significantly improved surface oxide, i.e., increased thickness and tunnel barrier height, compared to CP cavities. These results help explain the improved performance of N-doped cavities and give insights into the origin of the initial increasing Q with RF amplitude.
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