We report the results of a search for serendipitous [CII] 157.74$mu$m emitters at $zsim4.4$-$4.7$ using the Atacama Large Millimeter/submillimeter Array (ALMA). The search exploits the AS2UDS continuum survey, which covers ~50 arcmin$^2$ of the sky towards 695 luminous ($S_{870}gtrsim1$mJy) submillimeter galaxies (SMGs), selected from the SCUBA-2 Cosmology Legacy Survey (S2CLS) 0.96deg$^2$ Ultra Deep Survey (UDS) field. We detect ten candidate line emitters, with an expected false detection rate of ten percent. All of these line emitters correspond to 870$mu$m continuum-detected sources in AS2UDS. The emission lines in two emitters appear to be high-J CO, but the remainder have multi-wavelength properties consistent with [CII] from $zsimeq4.5$ galaxies. Using our sample, we place a lower limit of $>5times10^{-6}$Mpc$^{-3}$ on the space density of luminous ($L_{rm IR} simeq 10^{13}$Lsun) SMGs at $z=4.40$-$4.66$, suggesting $ge7$percent of SMGs with $S_{870mu{rm m}}gtrsim1$mJy lie at $4<z<5$. From stacking the high-resolution ($sim0.15$ full-width half maximum) ALMA $870mu$m imaging, we show that the [CII] line emission is more extended than the continuum dust emission, with an average effective radius for the [CII] of $r_{rm e} = 1.7^{+0.1}_{-0.2}$kpc compared to $r_{rm e} = 1.0pm0.1$kpc for the continuum (rest-frame $160mu$m). By fitting the far-infrared photometry for these galaxies from $100$-$870mu$m, we show that SMGs at $zsim4.5$ have a median dust temperature of $T_{rm d}=55pm4$K. This is systematically warmer than $870mu$m-selected SMGs at $zsimeq2$, which typically have temperatures around $35$K. These $zsimeq4.5$ SMGs display a steeper trend in the luminosity-temperature plane than $zle2$ SMGs. We discuss the implications of this result in terms of the selection biases of high redshift starbursts in far-infrared/submillimeter surveys.
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