Resonating valence bond (RVB) states are a class of entangled quantum many body wavefunctions with great significance in condensed matter physics. We propose a scheme to synthesize a family of RVB states using a cavity QED setup with two-level atoms (with states $vert 0 rangle$ and $vert 1 rangle$) coupled to a common photon mode. In the lossy cavity limit, starting with an initial state of $M$ atoms excited and $N$ atoms in the ground state, we show that this setup can be configured as a Stern Gerlach experiment. A measurement of photon emission collapses the wavefunction of atoms onto an RVB state composed of resonating long-ranged singlets of the form $frac{1}{sqrt{2}}[vert 0 1 rangle - vert 1 0 rangle]$. Each emitted photon reduces the number of singlets by unity, replacing it with a pair of lone spins or `spinons. As spinons are formed coherently in pairs, they are analogous to Cooper pairs in a superconductor. To simulate pair fluctuations, we propose a protocol in which photons are allowed to escape the cavity undetected. This leads to a mixed quantum state with a fluctuating number of spinon pairs -- an inchoate superconductor. Remarkably, in the limit of large system sizes, this protocol reveals an underlying quantum phase transition. Upon tuning the initial spin polarization ($M-N$), the emission exhibits a continuous transition from a dark state to a bright state. This is reflected in the spinon pair number distribution which can be tuned from sub-poissonian to super-poissonian regimes. This opens an exciting route to simulate RVB states and superconductivity.