A new Cr-based quasi-one-dimensional superconductor Na2Cr3As3 was synthesized by an ion-exchange method in sodium naphthalenide solution. The crystals are thread-like and the structure was analyzed by X-ray diffraction with a noncentrosymmetric hexagonal space group P-6m2 (No. 187), in which the (Cr3As3)2- linear chains are separated by Na+ ions, and the refined lattice parameters are a = 9.239(2) {AA} and c = 4.209(6) {AA}. The measurements for electrical resistivity, magnetic susceptibility, and heat capacity reveal a superconducting transition with unconventional characteristic at the Tc of 8.6 K, which exceeds that of all previously reported Cr-based superconductors.
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