The Magellanic Stream, a gaseous tail that trails behind the Magellanic Clouds, could replenish the Milky Way with a tremendous amount of gas if it reaches the Galactic disk before it evaporates into the halo. To determine how the Magellanic Streams properties change along its length, we have conducted an observational study of the H-alpha emission, along with other optical warm ionized gas tracers, toward 39 sight lines. Using the Wisconsin H-alpha Mapper telescope, we detect H-alpha emission brighter than 30 - 50 mR in 26 of our 39 sight lines. This H-alpha emission extends more than 2-degree away from the HI emission. By comparing H-alpha and [OI] intensities, we find that regions with log NHI = 19.5 - 20.0 are 16 - 67% ionized. Most of the H-alpha intensities along the Magellanic Stream are much higher than expected if the primary ionization source is photoionization from Magellanic Clouds, the Milky Way, and the extragalactic background. We find that the additional contribution from self ionization through a shock cascade that results as the Stream plows through the halo might be sufficient to reproduce the underlying level of H-alpha emission along the Stream. In the sparsely sampled region below the South Galactic Pole, there exists a subset of sight lines with uncharacteristically bright emission, which suggest that gas is being ionized further by an additional source that could be a linked to energetic processes associated with the Galactic center.
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