Polyvinylidenefluoride (PVDF) a semicrystalline pieozoelectric polymer was synthesized with varying process conditions and its ferroelectric domain orientations were studied using piezoresponse force microscope (PFM). PVDF thin films fabricated using tape casting technique with precursor solutions of varying viscosities reveal that the polarization components transform from a dominant planar component to an out-of-plane polarization components with increase in viscosity. Interestingly the planar components possessed a head to head or tail to tail kind of paired domains separated by a distance of ~ 380-400nm. The electrostatic energies computed by numerically solving the electrostatic equilibrium equation for the electrically inhomogeneous system are in good correlation with the experiments. On increment of electric field, the domains were observed to grow in size and shape which indicates amorphous to crystalline transformation in the case of PVDF. Such transformation was evident from x-ray diffraction studies performed in-situ in the presence of an applied electric field.
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