A laboratory experiment is suggested in which conditions similar to those in the plume ejecta from Enceladus and, perhaps, Europa are established. Using infrared spectroscopy and polarimetry, the experiment might identify possible bio-markers in differential measurements of water from the open-ocean, from hydrothermal vents, and abiotic water samples. Should the experiment succeed, large telescopes could be used to acquire sensitive infrared spectra of the plumes of Enceladus and Europa, as the satellites transit the bright planetary disks. The extreme technical challenges encountered in so doing are similar to those of solar imaging spectropolarimetry. The desired signals are buried in noisy data in the presence of seeing-induced image motion and a changing natural source. Some differential measurements used for solar spectropolarimetry can achieve S/N ratios of $10^5$ even in the presence of systematic errors two orders of magnitude larger. We review the techniques and likelihood of success of such an observing campaign with some of the worlds largest ground-based telescopes, as well as the long anticipated James Webb Space Telescope. We discuss the relative merits of the new 4m Daniel K. Inouye Solar Telescope, as well as the James Webb Space Telescope and larger ground-based observatories, for observing the satellites of giant planets. As seen from near Earth, transits of Europa occur regularly, but transits of Enceladus will begin again only in 2022.
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