A central goal within quantum optics is to realize efficient interactions between photons and atoms. A fundamental limit in nearly all applications based on such systems arises from spontaneous emission, in which photons are absorbed by atoms and then re-scattered into undesired channels. In typical treatments of atomic ensembles, it is assumed that this re-scattering occurs independently, and at a rate given by a single isolated atom, which in turn gives rise to standard limits of fidelity in applications such as quantum memories or quantum gates. However, this assumption can be violated. In particular, spontaneous emission of a collective atomic excitation can be significantly suppressed through strong interference in emission. Thus far the physics underlying the phenomenon of subradiance and techniques to exploit it have not been well-understood. In this work, we provide a comprehensive treatment of this problem. First, we show that in ordered atomic arrays in free space, subradiant states acquire an interpretation in terms of optical modes that are guided by the array, which only emit due to scattering from the ends of the finite chain. We also elucidate the properties of subradiant states in the many-excitation limit. Finally, we introduce the new concept of selective radiance. Whereas subradiant states experience a reduced coupling to all optical modes, selectively radiant states are tailored to simultaneously radiate efficiently into a desired channel while scattering into undesired channels is suppressed, thus enabling an enhanced atom-light interface. We show that these states naturally appear in chains of atoms coupled to nanophotonic structures, and we analyze the performance of photon storage exploiting such states. We find that selectively radiant states allow for a photon storage error that scales exponentially better with number of atoms than previously known bounds.
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