Bells theorem was a cornerstone for our understanding of quantum theory, and the establishment of Bell non-locality played a crucial role in the development of quantum information. Recently, its extension to complex networks has been attracting a growing attention, but a deep characterization of quantum behaviour is still missing for this novel context. In this work we analyze quantum correlations arising in the bilocality scenario, that is a tripartite quantum network where the correlations between the parties are mediated by two independent sources of states. First, we prove that non-bilocal correlations witnessed through a Bell-state measurement in the central node of the network form a subset of those obtainable by means of a separable measurement. This leads us to derive the maximal violation of the bilocality inequality that can be achieved by arbitrary two-qubit quantum states and arbitrary projective separable measurements. We then analyze in details the relation between the violation of the bilocality inequality and the CHSH inequality. Finally, we show how our method can be extended to n-locality scenario consisting of n two-qubit quantum states distributed among n+1 nodes of a star-shaped network.
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