A new mechanism of nuclear excitation via two-photon electron transitions (NETP) is proposed and studied theoretically. As a generic example, detailed calculations are performed for the $E1E1$ $1s2s,^1S_0 rightarrow 1s^2,^1S_0$ two-photon decay of He-like $^{225}$Ac$^{87+}$ ion with the resonant excitation of the $3/2+$ nuclear state with the energy 40.09(5) keV. The probability for such a two-photon decay via the nuclear excitation is found to be $P_{rm NETP} = 3.5 times 10^{-9}$ and, thus, is comparable with other mechanisms, such as nuclear excitation by electron transition and by electron capture. The possibility for the experimental observation of the proposed mechanism is thoroughly discussed.
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