We report the detection of the Zeeman effect in the 44 GHz Class I methanol maser line toward the star forming region DR21(OH). In a 219 Jy/beam maser centered at an LSR velocity of 0.83 km s$^{-1}$, we find a 20-$sigma$ detection of $zB_{text{los}} = 53.5 pm 2.7$ Hz. If 44 GHz methanol masers are excited at $n sim 10^{7-8}$ cm$^{-3}$, then the $B~vs.~n^{1/2}$ relation would imply from comparison with Zeeman effect detections in the CN($1-0$) line toward DR21(OH) that magnetic fields traced by 44 GHz methanol masers in DR21(OH) should be $sim$10 mG. Together with our detected $zB_{text{los}} = 53.5$ Hz, this would imply that the value of the 44 GHz methanol Zeeman splitting factor $z$ is $sim$5 Hz mG$^{-1}$. Such small values of $z$ would not be a surprise, as the methanol molecule is non paramagnetic, like H$_2$O. Empirical attempts to determine $z$, as demonstrated, are important because currently there are no laboratory measurements or theoretically calculated values of $z$ for the 44 GHz methanol transition. Data from observations of a larger number of sources are needed to make such empirical determinations robust.
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