Quantal diffusion mechanism of nucleon exchange is studied in the central collisions of several symmetric heavy-ion collisions in the framework of the Stochastic Mean-Field (SMF) approach. Since at bombarding energies below the fusion barrier, di-nuclear structure is maintained, it is possible to describe nucleon exchange as a diffusion process familiar from deep-inelastic collisions. Quantal diffusion coefficients, including memory effects, for proton and neutron exchanges are extracted microscopically employing the SMF approach. The quantal calculations of neutron and proton variances are compared with the semi-classical results.