We analyse the nature of spontaneous symmetry breaking in complex quantum systems by investigating the long-standing conjecture that the maximally symmetry-breaking quantum ground states are the most classical ones corresponding to a globally ordered phase. We make this argument quantitatively precise by comparing different local and global indicators of classicality and quantumness, respectively in symmetry-breaking and symmetry-preserving quantum ground states. We first discuss how naively comparing local, pairwise entanglement and discord apparently leads to the opposite conclusion. Indeed, we show that in symmetry-preserving ground states the two-body entanglement captures only a modest portion of the total two-body quantum correlations, while, on the contrary, in maximally symmetry-breaking ground states it contributes the largest amount to the total two-body quantum correlations. We then put to test the conjecture by looking at the global, macroscopic correlation properties of quantum ground states. We prove that the ground states which realize the maximum breaking of the Hamiltonian symmetries, associated to a globally ordered phase, are the only ones that: I) are always locally convertible, i.e. can be obtained from all other ground states by only applying LOCC transformations (local operations and classical communication), while the reverse is never possible; II) minimize the monogamy inequality on the globally shared, macroscopic bipartite entanglement.
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