We employ new calculational technique and present complete list of classical $r$-matrices for $D=4$ complex homogeneous orthogonal Lie algebra $mathfrak{o}(4;mathbb{C})$, the rotational symmetry of four-dimensional complex space-time. Further applying reality conditions we obtain the classical $r$-matrices for all possible real forms of $mathfrak{o}(4;mathbb{C})$: Euclidean $mathfrak{o}(4)$, Lorentz $mathfrak{o}(3,1)$, Kleinian $mathfrak{o}(2,2)$ and quaternionic $mathfrak{o}^{star}(4)$ Lie algebras. For $mathfrak{o}(3,1)$ we get known four classical $D=4$ Lorentz $r$-matrices, but for other real Lie algebras (Euclidean, Kleinian, quaternionic) we provide new results and mention some applications.
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