We investigate strategies for increasing the thermopower of crown-ether-bridged anthraquinones. The novel design feature of these molecules is the presence of either (1) crown-ether or (2) diaza-crown-ether bridges attached to the side of the current-carrying anthraquinone wire. The crown-ether side groups selectively bind alkali- metal cations and when combined with TCNE or TTF dopants, provide a large phase-space for optimising thermoelectric properties. We find that the optimum combination of cations and dopants depends on the temperature range of interest. The thermopowers of both 1 and 2 are negative and at room temperature are optimised by binding with TTF alone, achieving thermpowers of -600 microvolts/K and -285 microvolts/K respectively. At much lower temperatures, which are relevant to cascade coolers, we find that for 1, a combination of TTF and Na+ yields a maximum thermopower of -710 microvolts/K at 70K, whereas a combination of TTF and Li+ yields a maximum thermopower of -600 microvolts/K at 90K. For 2, we find that TTF doping yields a maximum thermopower of -800 microvolts/K at 90K, whereas at 50K, the largest thermopower (of -600 microvolts/K) is obtain by a combination TTF and K+ doping. At room temperature, we obtain power factors of 73 microwatts/m.K2 for 1 (in combination with TTF and Na+ ) and 90 microwatts/m.K2 for 2 (with TTF). These are higher or comparable with reported power factors of other organic materials.
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