We discuss the role of Poisson-Nijenhuis geometry in the definition of multiplicative integrable models on symplectic groupoids. These are integrable models that are compatible with the groupoid structure in such a way that the set of contour levels of the hamiltonians in involution inherits a topological groupoid structure. We show that every maximal rank PN structure defines such a model. We consider the examples defined on compact hermitian symmetric spaces and studied in [arXiv:1503.07339].