The Gupta-Bleuler triplet for vector-spinor gauge field is presented in de Sitter ambient space formalism. The invariant space of field equation solutions is obtained with respect to an indecomposable representation of the de Sitter group. By using the general solution of the massless spin-$frac{3}{2}$ field equation, the vector-spinor quantum field operator and its corresponding Fock space is constructed. The quantum field operator can be written in terms of the vector-spinor polarization states and a quantum conformally coupled massless scalar field, which is constructed on Bunch-Davies vacuum state. The two-point function is also presented, which is de Sitter covariant and analytic.