Pure states are very important in any theory since they represent states of maximal information about the system within the theory. Here, we show that no non-trivial (not local realistic) extremal states (boxes) of general no-signaling theories can be realized within quantum theory. We then explore three interesting consequences of this fact. Firstly, since the pure states are uncorrelated from the environment, the statement forms a no-go result against the most straightforward device-independent protocol for randomness or secure key generation against general no-signaling adversaries. It also leads to the interesting question whether all non-extremal boxes allow for non-local correlations with the adversary. Secondly, in addition to the fact that new information-theoretic principles (designed to pick out the set of quantum correlations from among all non signaling ones) can in consequence be tested on arbitrary non-local vertices to check their validity, it also allows the possibility of excluding from the quantum set any box of no-signaling correlations that can be distilled to a non-local vertex. Finally, it also forms a sufficient condition to identify non-local games with no quantum winning strategy, when one can show that the game has a single unique non-signaling winning strategy. We illustrate each of these consequences with the example of generalized Popescu-Rohrlich boxes.
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