The Exozodi survey aims to determine the occurrence rate of bright exozodiacal discs around nearby main sequence stars using infrared interferometry. Although the Exozodi survey targets have been carefully selected to avoid the presence of binary stars, the results of this survey can still be biased by the presence of unidentified stellar companions. Using the PIONIER data set collected within the Exozodi survey, we aim to search for the signature of point-like companions around the Exozodi target stars. We use both the closure phases and squared visibilities collected by PIONIER to search for companions within the ~100 mas interferometric field of view. The presence of a companion is assessed by computing the goodness of fit to the data for a series of binary models with various separations and contrasts. Five stellar companions are resolved for the first time around five A-type stars: HD 4150, HD 16555, HD 29388, HD 202730, and HD 224392 (although the companion to HD 16555 was independently resolved by speckle interferometry while we were carrying out the survey). In the most likely case of main sequence companions, their spectral types range from A5V to K4V. Three of these stars were already suspected to be binaries from Hipparcos astrometric measurements, although no information was available on the companions themselves so far. In addition to debiasing the statistics of the Exozodi survey, these results can also be used to revise the fraction of visual binaries among A-type stars, suggesting that an extra ~13% A-type stars are visual binaries in addition to the ones detected in previous direct imaging surveys. We estimate that about half the population of nearby A-type stars could be resolved as visual binaries using a combination of state-of-the-art interferometry and single-aperture imaging, and we suggest that a significant fraction of these binaries remains undetected to date.