Controlling the decoherence induced by the interaction of quantum system with its environment is a fundamental challenge in quantum technology. Utilizing Floquet theory, we explore the constructive role of temporal periodic driving in suppressing decoherence of a spin-1/2 particle coupled to a spin bath. It is revealed that, accompanying the formation of a Floquet bound state in the quasienergy spectrum of the whole system including the system and its environment, the dissipation of the spin system can be inhibited and the system tends to coherently synchronize with the driving. It can be seen as an analog to the decoherence suppression induced by the structured environment in spatially periodic photonic crystal setting. Comparing with other decoherence control schemes, our protocol is robust against the fluctuation of control parameters and easy to realize in practice. It suggests a promising perspective of periodic driving in decoherence control.