The issue of interference and which-way information is addressed in the context of 3-slit interference experiments. A new path distinguishability ${mathcal D_Q}$ is introduced, based on Unambiguous Quantum State Discrimination (UQSD). An inequality connecting the interference visibility and path distinguishability, ${mathcal V} + {2{mathcal D_Q}over 3- {mathcal D_Q}} le 1$, is derived which puts a bound on how much fringe visibility and which-way information can be simultaneously obtained. It is argued that this bound is tight. For 2-slit interference, we derive a new duality relation which reduces to Englerts duality relation and Greenberger-Yasins duality relation, in different limits.
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