Present experimental datas have shown a 3.8$sigma$ level discrepancy with the standard model in $overline{B}to D^{(*)}taubar{ u}_{tau}$. Some new physics models have been considered to explain this discrepancy possibly with new source of the CP violation. In this paper, we construct CP violating observables by using multi-pion decays in $Bto Dtau u_{tau}$, and estimate sensitivity of these observables to generic CP violating operators. We also discuss possibilities of CP violation in leptoquark models and in 2HDM of type-III.