First observations of the decays $Lambda_b^0 to Lambda_c^+ D_{(s)}^-$ are reported using data corresponding to an integrated luminosity of $3,{rm fb}^{-1}$ collected at 7 and 8 TeV center-of-mass energy in proton-proton collisions with the LHCb detector. In addition, the most precise measurement of the branching fraction ${mathcal{B}(B_s^0 to D^+D_s^-)}$ is made and a search is performed for the decays $B^0_{(s)} to Lambda_c^+ Lambda_c^-$. The results obtained are begin{eqnarray*} mathcal{B}(Lambda_b^0 to Lambda_c^+ D^-)/mathcal{B}(Lambda_b^0 to Lambda_c^+ D_{s}^-) &=& 0.042 pm 0.003({rm stat}) pm 0.003({rm syst}), left[frac{mathcal{B}(Lambda_b^0 to Lambda_c^+ D_{s}^-)}{mathcal{B}({kern 0.2em}overline{kern -0.2em B}_d^0 to D^+D_s^-)}right]big/left[frac{mathcal{B}(Lambda_b^0 to Lambda_c^+pi^-)}{mathcal{B}({kern 0.2em}overline{kern -0.2em B}_d^0 to D^+pi^-)}right] &=& 0.96 pm 0.02({rm stat}) pm 0.06({rm syst}), mathcal{B}(B_s^0 to D^+D_s^-)/mathcal{B}({kern 0.2em}overline{kern -0.2em B}_d^0 to D^+D_s^-) &=& 0.038pm0.004({rm stat})pm0.003({rm syst}), mathcal{B}({kern 0.2em}overline{kern -0.2em B}^0 to Lambda_c^+ Lambda_c^-)/mathcal{B}({kern 0.2em}overline{kern -0.2em B}_d^0 to D^+D_s^-) & < & 0.0022; [95% ; {rm C.L.}], mathcal{B}(B^0_{s} to Lambda_c^+ Lambda_c^-)/mathcal{B}(B_s^0 to D^+D_s^-) & < & 0.30; [95% ; {rm C.L.}]. end{eqnarray*} Measurement of the mass of the $Lambda_b^0$ baryon relative to the $B^0$ meson gives ${M(Lambda_b^0) -M(B^0) = 339.72pm 0.24({rm stat}) pm 0.18({rm syst})}$ MeV$/c^2$. This result provides the most precise measurement of the mass of the $Lambda_b^0$ baryon to date.