We present a comprehensive investigation of the Epsilon Chamaeleontis association (Epsilon Cha), one of several young moving groups spread across the southern sky. We re-assess the putative membership of Epsilon Cha using the best-available proper motion and spectroscopic measurements, including new ANU 2.3-m/WiFeS observations. After applying a kinematic analysis our final membership comprises 35-41 stars from B9 to mid-M spectral types, with a mean distance of 110+/-7 pc and a mean space motion of (U,V,W)=(-10.9+/-0.8,-20.4+/-1.3,-9.9+/-1.4) km/s. Theoretical evolutionary models suggest Epsilon Cha is 3-5 Myr old, distinguishing it as the youngest moving group in the solar neighbourhood. Fifteen members show 3-22 micron spectral energy distributions attributable to circumstellar discs, including 11 stars which appear to be actively accreting. Epsilon Chas disc and accretion fractions (29+8-6 and 32+9-7 per cent, respectively) are both consistent with a typical 3-5 Myr-old population. Multi-epoch spectroscopy reveals three M-type members with broad and highly-variable H-alpha emission as well as several new spectroscopic binaries. We reject 11 stars proposed as members in the literature and suggest they may belong to the background Cha I and II clouds or other nearby young groups. Our analysis underscores the importance of a holistic and conservative approach to assigning young stars to kinematic groups, many of which have only subtly different properties and ill-defined memberships. We conclude with a brief discussion of Epsilon Chas connection to the young open cluster Eta Cha and the Sco-Cen OB association. Contrary to earlier studies which assumed Eta and Epsilon Cha are coeval and were born in the same location, we find the groups were separated by ~30 pc when Eta Cha formed 4-8 Myr ago in the outskirts of Sco-Cen, 1-3 Myr before the majority of Epsilon Cha members.
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