We investigated the Abrikosov vortex lattice (VL) of a pure Niobium single crystal with the muon spin rotation (mu SR) technique. Analysis of the mu SR data in the framework of the BCS-Gorkov theory allowed us to determine microscopic parameters and the limitations of the theory. With decreasing temperature the field variation around the vortex cores deviates substantially from the predictions of the Ginzburg-Landau theory and adopts a pronounced conical shape. This is evidence of partial diffraction of Cooper pairs on the VL predicted by Delrieu for clean superconductors.