We describe the application of Raman Optical-fiber Amplification (ROA) for the phase coherent transfer of optical frequencies in an optical fiber link. ROA uses the transmission fiber itself as a gain medium for bi-directional coherent amplification. In a test setup we evaluated the ROA in terms of on-off gain, signal-to-noise ratio, and phase noise added to the carrier. We transferred a laser frequency in a 200 km optical fiber link with an additional 16 dB fixed attenuator (equivalent to 275 km of fiber on a single span), and evaluated both co-propagating and counter-propagating amplification pump schemes, demonstrating nonlinear effects limiting the co-propagating pump configuration. The frequency at the remote end has a fractional frequency instability of 3e-19 over 1000 s with the optical fiber link noise compensation.