We present a Giant Molecular Cloud (GMC) catalog toward M33, containing 71 GMCs in total, based on wide field and high sensitivity CO(J=3-2) observations with a spatial resolution of 100 pc using the ASTE 10 m telescope. Employing archival optical data, we identify 75 young stellar groups (YSGs) from the excess of the surface stellar density, and estimate their ages by comparing with stellar evolution models. A spatial comparison among the GMCs, YSGs, and HII regions enable us to classify GMCs into four categories: Type A showing no sign of massive star formation (SF), Type B being associated only with HII regions, Type C with both HII regions and <10 Myr-old YSGs and Type-D with both HII regions and 10--30 Myr YSGs. Out of 65 GMCs (discarding those at the edges of the observed fields), 1 (1%), 13 (20%), 29 (45%), and 22 (34%) are Types A, B, C, and D, respectively. We interpret these categories as stages in a GMC evolutionary sequence. Assuming that the timescale for each evolutionary stage is proportional to the number of GMCs, the lifetime of a GMC with a mass >10^5 Mo is estimated to be 20--40 Myr. In addition, we find that the dense gas fraction as traced by the CO(J=3-2)/CO(J=1-0) ratio is enhanced around SF regions. This confirms a scenario where dense gas is preferentially formed around previously generated stars, and will be the fuel for the next stellar generation. In this way, massive SF gradually propagates in a GMC until gas is exhausted.
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