A wide class of binary-state dynamics on networks---including, for example, the voter model, the Bass diffusion model, and threshold models---can be described in terms of transition rates (spin-flip probabilities) that depend on the number of nearest neighbors in each of the two possible states. High-accuracy approximations for the emergent dynamics of such models on uncorrelated, infinite networks are given by recently-developed compartmental models or approximate master equations (AME). Pair approximations (PA) and mean-field theories can be systematically derived from the AME. We show that PA and AME solutions can coincide under certain circumstances, and numerical simulations confirm that PA is highly accurate in these cases. For monotone dynamics (where transitions out of one nodal state are impossible, e.g., SI disease-spread or Bass diffusion), PA and AME give identical results for the fraction of nodes in the infected (active) state for all time, provided the rate of infection depends linearly on the number of infected neighbors. In the more general non-monotone case, we derive a condition---that proves equivalent to a detailed balance condition on the dynamics---for PA and AME solutions to coincide in the limit $t to infty$. This permits bifurcation analysis, yielding explicit expressions for the critical (ferromagnetic/paramagnetic transition) point of such dynamics, closely analogous to the critical temperature of the Ising spin model. Finally, the AME for threshold models of propagation is shown to reduce to just two differential equations, and to give excellent agreement with numerical simulations. As part of this work, Octave/Matlab code for implementing and solving the differential equation systems is made available for download.
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