GRB110721A was observed by the Fermi Gamma-ray Space Telescope using its two instruments the Large Area Telescope (LAT) and the Gamma-ray Burst Monitor (GBM). The burst consisted of one major emission episode which lasted for ~24.5 seconds (in the GBM) and had a peak flux of 5.7pm0.2 x 10^{-5} erg/s/cm^2. The time-resolved emission spectrum is best modeled with a combination of a Band function and a blackbody spectrum. The peak energy of the Band component was initially 15pm2 MeV, which is the highest value ever detected in a GRB. This measurement was made possible by combining GBM/BGO data with LAT Low Energy Events to achieve continuous 10--100 MeV coverage. The peak energy later decreased as a power law in time with an index of -1.89pm0.10. The temperature of the blackbody component also decreased, starting from ~80 keV, and the decay showed a significant break after ~2 seconds. The spectrum provides strong constraints on the standard synchrotron model, indicating that alternative mechanisms may give rise to the emission at these energies.
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