In this paper we investigate the derivations of filiform Leibniz algebras. Recall that the set of filiform Leibniz algebras of fixed dimension is decomposed into three non-intersected families. We found sufficient conditions under which filiform Leibniz algebras of the first family are characteristically nilpotent. Moreover, for the first family we classify non-characteristically nilpotent algebras by means of Catalan numbers. In addition, for the rest two families of filiform Leibniz algebras we describe non-characteristically nilpotent algebras, i.e., those filiform Leibniz algebras which lie in the complementary set to those characteristically nilpotent.