We present the largest sample of spectroscopically confirmed X-ray luminous high-redshift galaxy clusters to date comprising 22 systems in the range 0.9<z<sim1.6 as part of the XMM-Newton Distant Cluster Project (XDCP). All systems were initially selected as extended X-ray sources over 76.1 deg^2 of non-contiguous deep archival XMM-Newton coverage. We test and calibrate the most promising two-band redshift estimation techniques based on the R-z and z-H colors for efficient distant cluster identifications and find a good redshift accuracy performance of the z-H color out to at least zsim1.5, while the redshift evolution of the R-z color leads to increasingly large uncertainties at z>sim0.9. We present first details of two newly identified clusters, XDCP J0338.5+0029 at z=0.916 and XDCP J0027.2+1714 at z=0.959, and investigate the Xray properties of SpARCS J003550-431224 at z=1.335, which shows evidence for ongoing major merger activity along the line-of-sight. We provide X-ray properties and luminosity-based total mass estimates for the full sample, which has a median system mass of M200simeq2times10^14Modot. In contrast to local clusters, the z>0.9 systems do mostly not harbor central dominant galaxies coincident with the X-ray centroid position, but rather exhibit significant BCG offsets from the X-ray center with a median value of about 50 kpc in projection and a smaller median luminosity gap to the second-ranked galaxy of sim0.3mag. We estimate a fraction of cluster-associated NVSS 1.4GHz radio sources of about 30%, preferentially located within 1 from the X-ray center. The galaxy populations in z>sim1.5 cluster environments show first evidence for drastic changes on the high-mass end of galaxies and signs for a gradual disappearance of a well-defined cluster red-sequence as strong star formation activity is observed in an increasing fraction of massive galaxies down to the densest core regions.
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