Using 586 $textrm{pb}^{-1}$ of $e^{+}e^{-}$ collision data acquired at $sqrt{s}=4.170$ GeV with the CLEO-c detector at the Cornell Electron Storage Ring, we report the first observation of $D_{s}^{*+} to D_{s}^{+} e^{+} e^{-}$ with a significance of $5.3 sigma$. The ratio of branching fractions $calB(D_{s}^{*+} to D_{s}^{+} e^{+} e^{-}) / calB(D_{s}^{*+} to D_{s}^{+} gamma)$ is measured to be $[ 0.72^{+0.15}_{-0.13} (textrm{stat}) pm 0.10 (textrm{syst})]%$, which is consistent with theoretical expectations.