We discuss the relevance of higher order moments of net baryon number fluctuations for the analysis of freeze-out and critical conditions in heavy ion collisions at LHC and RHIC. Using properties of O(4) scaling functions, we discuss the generic structure of these higher moments at vanishing baryon chemical potential and apply chiral model calculations to explore their properties at non-zero baryon chemical potential. We show that the ratios of the sixth to second and eighth to second order moments of the net baryon number fluctuations change rapidly in the transition region of the QCD phase diagram. Already at vanishing baryon chemical potential they deviate considerably from the predictions of the hadron resonance gas model which reproduce the second to fourth order moments of the net proton number fluctuations at RHIC. We point out that the sixth order moments of baryon number and electric charge fluctuations remain negative at the chiral transition temperature. Thus, they offer the possibility to probe the proximity of the thermal freeze-out to the crossover line.
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