Rajchman measures of locally compact Abelian groups are studied for almost a century now, and they play an important role in the study of trigonometric series. Eymards influential work allowed generalizing these measures to the case of emph{non-Abelian} locally compact groups $G$. The Rajchman algebra of $G$, which we denote by $B_0(G)$, is the set of all elements of the Fourier-Stieltjes algebra that vanish at infinity. In the present article, we characterize the locally compact groups that have amenable Rajchman algebras. We show that $B_0(G)$ is amenable if and only if $G$ is compact and almost Abelian. On the other extreme, we present many examples of locally compact groups, such as non-compact Abelian groups and infinite solvable groups, for which $B_0(G)$ fails to even have an approximate identity.
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