Many early-type stars are in binary systems. A number of them shows radio emissivity with periodic variability. This variability is associated with non-thermal synchrotron radiation emitted by relativistic electrons. The strong shocks necessary to accelerate the electrons up to high energies are produced by the collision of the radiatively-driven stellar winds. A study of the non-thermal emission is necessary in order to investigate O-star colliding wind binaries. Here preliminary results of our modeling of the colliding winds in Cyg OB2 No.9 are presented.