We have derived Fe abundances of 16 solar-type Pleiades dwarfs by means of an equivalent width analysis of Fe I and Fe II lines in high-resolution spectra obtained with the Hobby - Eberly Telescope and High Resolution Spectrograph. Abundances derived from Fe II lines are larger than those derived from Fe I lines (herein referred to as over-ionization) for stars with Teff < 5400 K, and the discrepancy (deltaFe = [Fe II/H] - [Fe I/H]) increases dramatically with decreasing Teff, reaching over 0.8 dex for the coolest stars of our sample. The Pleiades joins the open clusters M 34, the Hyades, IC 2602, and IC 2391, and the Ursa Major moving group, demonstrating ostensible over-ionization trends. The Pleiades deltaFe abundances are correlated with Ca II infrared triplet and Halpha chromospheric emission indicators and relative differences therein. Oxygen abundances of our Pleiades sample derived from the high-excitation O I triplet have been previously shown to increase with decreasing Teff, and a comparison with the deltaFe abundances suggests that the over-excitation (larger abundances derived from high excitation lines relative to low excitation lines) and over-ionization effects that have been observed in cool open cluster and disk field main sequence (MS) dwarfs share a common origin. Star-to-star Fe I abundances have low internal scatter, but the abundances of stars with Teff < 5400 K are systematically higher compared to the warmer stars. The cool star [Fe I/H] abundances cannot be connected directly to over-excitation effects, but similarities with the deltaFe and O I triplet trends suggest the abundances are dubious. Using the [Fe I/H] abundances of five stars with Teff > 5400 K, we derive a mean Pleiades cluster metallicity of [Fe/H] = +0.01 +/- 0.02.
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