How do we uniquely identify a quantum phase, given its ground state wave-function? This is a key question for many body theory especially when we consider phases like topological insulators, that share the same symmetry but differ at the level of topology. The entanglement spectrum has been proposed as a ground state property that captures characteristic edge excitations. Here we study the entanglement spectrum for topological band insulators. We first show that insulators with topological surface states will necessarily also have protected modes in the entanglement spectrum. Surprisingly, however, the converse is not true. Protected entanglement modes can also appear for insulators without physical surface states, in which case they capture a more elusive property. This is illustrated by considering insulators with only inversion symmetry. Inversion is shown to act in an unusual way, as an antiunitary operator, on the entanglement spectrum, leading to this protection. The entanglement degeneracies indicate a variety of different phases in inversion symmetric insulators, and these phases are argued to be robust to the introduction of interactions.
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