We investigate the sample of 213 GPS sources selected from simultaneous multi-frequency 1-22 GHz observations obtained with RATAN-600 radio telescope. We use publicly available data to characterize parsec-scale structure of the selected sources. Among them we found 121 core dominated sources, 76 Compact Symmetric Object (CSO) candidates (24 of them are highly probable), 16 sources have complex parsec-scale morphology. Most of GPS galaxies are characterized by CSO-type morphology and lower observed peak frequency (~1.8 GHz). Most of GPS quasars are characterized by core-jet-type morphology and higher observed peak frequency (~3.6 GHz). This is in good agreement with previous results. However, we found a number of sources for which the general relation CSO - galaxy, core-jet - quasar does not hold. These sources deserve detailed investigation. Assuming simple synchrotron model of a homogeneous cloud we estimate characteristic magnetic field in parsec-scale components of GPS sources to be B ~ 10 mG.