We present the results of a targeted 3-mm spectral line survey towards the eighty-three 6.67 GHz methanol maser selected star forming clumps observed by Purcell et al. 2006. In addition to the previously reported measurements of HCO+ (1 - 0), H13CO+ (1 - 0), and CH3CN (5 - 4) & (6 -5), we used the Mopra antenna to detect emission lines of N2H+ (1 - 0), HCN (1 - 0) and HNC (1 - 0) towards 82/83 clumps (99 per cent), and CH3OH (2 - 1) towards 78/83 clumps (94 per cent). The molecular line data have been used to derive virial and LTE masses, rotational temperatures and chemical abundances in the clumps, and these properties have been compared between sub-samples associated with different indicators of evolution. The greatest differences are found between clumps associated with 8.6 GHz radio emission, indicating the presence of an Ultra-Compact HII region, and `isolated masers (without associated radio emission), and between clumps exhibiting CH3CN emission and those without. In particular, thermal CH3OH is found to be brighter and more abundant in Ultra-Compact HII (UCHII) regions and in sources with detected CH3CN, and may constitute a crude molecular clock in single dish observations. Clumps associated with 8.6 GHz radio emission tend to be more massive and more luminous than clumps without radio emission. This is likely because the most massive clumps evolve so rapidly that a Hyper-Compact HII or UCHII region is the first visible tracer of star-formation. The gas-mass to sub-mm/IR luminosity relation for the combined sample was found to be L proportional to M**0.68, considerably shallower than expected for massive main-sequence stars.
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