We examine possibilities of pion condensation with zero momentum (s-wave condensation) in neutron stars by using the pion-nucleus optical potential U and the relativistic mean field (RMF) models. We use low-density phenomenological optical potentials parameterized to fit deeply bound pionic atoms or pion-nucleus elastic scatterings. Proton fraction (Y_p) and electron chemical potential (mu_e) in neutron star matter are evaluated in RMF models. We find that the s-wave pion condensation hardly takes place in neutron stars and especially has no chance if hyperons appear in neutron star matter and/or b_1 parameter in U has density dependence.
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