We compute the difference in decay widths of charged and neutral rho(770) vector mesons. The isospin breaking arising from mass differences of neutral and charged pi and rho mesons, radiative corrections to rho -> pipi, and the rho -> pipigamma decays are taken into account. It is found that the width difference Delta Gamma_rho is very sensitive ot the isospin breaking in the $rho$ meson mass Delta m_rho. This result can be useful to test the correlations observed between the values of these parameters extracted from experimental data.
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